Effect Of An Alkyl Group And Solvent

A continuous-distribution kinetic model with midpoint scission was used to determine the rate coefficients.

This was explained based on the delocalization of charge on the carbon atoms joining two monomer units. The effect of temperature and solvents on the ultrasonic degradation of PBA was also investigated.

The degradation rate coefficient decreased with an increase in the vapor pressure of the solvent and with an increase in the temperature. The degradation rate decreased with an increase in the AIBN concentration, and the experimental results were simulated by the model. Fax: E-mail: [email protected] Cited By This article is cited by 17 publications.

Preston A. May, Nicholas F. Munaretto, Michael B. Hamoy, Maxwell J. Robb, and Jeffrey S. ACS Macro Letters5 2 Gomez, and Megan L. Macromolecules46 18]

Effect Of An Alkyl Group And Solvent Video

Effect of structure of alkyl group on SN1 \u0026 SN2 Effect Of An Alkyl Group And Solvent.

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Chemistry Synthetic Metals Abstract In poly 3- n -alkylthiophene P3AT , the length of alkyl side chain as well as the solvent used for film casting affected the conformation and eventually the luminescent characteristics of the polymers. When the length of alkyl side chain was shorter than 12 carbon atoms, the electronic absorption and PL spectra of P3AT film showed red shift as the length of the alkyl side chain increased. This is because, when the length of the alkyl side chain is not too long, solvation is promoted… Expand.